|
Symbol
|
Ag
|
|
Atomic number
|
47
|
|
Atomic mass
|
107.87 g.mol -1
|
|
Electronegativity according
to Pauling
|
1.9
|
|
Density
|
10.5 g.cm-3 at 20°C
|
|
Melting point
|
962 °C
|
|
Boiling point
|
2212 °C
|
|
Vanderwaals
radius
|
0.144 nm
|
|
Ionic radius
|
0.126 nm
|
|
Isotopes
|
11
|
|
Electronic shell
|
[ Kr ] 4d10 5s1
|
|
Energy of first
ionization
|
758 kJ.mol -1
|
|
Energy of second
ionization
|
2061 kJ.mol -1
|
Silver
Pure silver is nearly white, lustrous, soft, very ductile, malleable,
it is an excellent conductor of heat and electricity. It is not a
chemically active metal, but it is attacked by nitric acid
(forming the nitrate) and by hot concentrated sulfuric acid. It has the
highest electrical conductivity of all metals, but its greater cost has
prevented it from being widely used for electrical purposes.
Silver is almost always monovalent in its compounds, but an oxide, a
fluoride, and a sulfide of divalent silver are known. It does not
oxidize in air but reacts with the hydrogen sulfide present in the air,
forming silver sulfide (tarnish). This is why silver objects need
regular cleaning. Silver is stable in water.
Applications
The principal use of silver is as a precious metal and its halide
salts, especially silver nitrate, are also widely used in photography.
The major outlets are photography, the electrical and electronic
industries and for domestic uses as cutlery, jewellery and mirrors.
Both colour and black and white images have relied on silver since the
early days of photography: siver bromide and silver iodide are sensitive
to light. When light strikes a film coated with one of these compounds,
some of the silver ions revert to the metal in tiny nuclei and the film
is developed with a reducing agent which causes more silver to deposit
on these nuclei. When the negative has the desired intensity, the
uneffected silver bromide or iodide is removed by dissoving in a fixing
agent, leaving the image behind.
Silver is also employed in the electrical industry: printed circuits are
made using silver paints, and computer keyboards use silver electrical
contacts.
Silver's catalytic properties make it ideal for use as a catalyst in
oxidation reactions. Other applications are in dentistry and in
high-capacity zinc long-life batteries.
Silver in the environment
Silver levels in soil are not usually high except in mineral-rich
areas when they can sometimes be as much as 44 ppm. Plants can absorb
silver and measured levels come in the range 0.03-0.5 ppm.
Metallic silver occurs naturally as crystals, but more generally as a
compact mass; there are small deposits in Norway, Germany and Mexico.
The chief silver ores are acanthite mined in Mexico, Bolivia and
Honduras, and stephanite, mined in Canada. However silver is mostly
obtained as a byproduct in the refining of other metals.
World production of newly mined silver is around 17.000 tonnes per year,
of which only about a quarter comes from silver mines. The rest is a
byproduct of refining other metals.
Back to
the periodic table of elements