|
Symbol
|
Rh
|
|
Atomic number |
45 |
|
Atomic mass |
102.91 g.mol -1 |
|
Electronegativity
according to Pauling |
2.2 |
|
Density |
12.4 g.cm-3 at 20°C |
|
Melting point |
1970 °C |
|
Boiling point |
3727 °C |
|
Isotopes |
9 |
|
Electronic shell |
[ Kr ] 4d8 5s1 |
|
Energy of first
ionisation |
742 kJ.mol -1 |
|
Standard Potential |
0.6 V |
Rhodium
Rhodium, together with ruthenium,
palladium, osmium,
iridium, and platinum form
a group of elements referred to as the platinum group metals (PGM).
Rhodium metal is lustrous and silvery white. Rhodium has a higher
melting point and lower density than platinum. It has a high reflectance
and is hard and durable. Upon heating it turns to the oxide when red and
at higher temperatures turns back to the element. Rhodium it is
unaffected by air and water up to 600 C. It is insoluble in most
acids, including aqua regia, but is dissolved in hot concentrated
sulfuric acid and it is attacked by molten alkalis.
Applications
Most metal (85%) goes into catalytic converters for cars. The major
use of the metal is in alloys with platinum and
iridium, giving
improved high-temperature strength and oxidation resistance. These
alloys are used in furnace windings, pen nibs, phonograph needles,
high-temperature thermocouple and resistance wires, electrodes for
aircraft spark plugs, bearings and electrical contacts.
The metal itself,is used to plate jewelry and the reflectors of
searchlights, due to its brilliance and resistance to tarnish,
It is also a highly useful catalyst in a number of industrial processes,
such as the BP-Monsanto process.
Rhodium in the environment
Rodhium occurs as rare deposits of the uncombined metal, for example
in Montana, USA and in rare minerals. The metal, which is available
commercialy, comes as a by product of the refining of certain copper and
nickel ores which can contain up to 0.1% rhodium. Most rhodium comes
from South Africa and Russia, and world production is around 16 toone
per year. Estimated reserves are 3.000 tonnes.
Back to
the periodic table of elements