|
Symbol
|
Pd
|
|
Atomic number
|
46
|
|
Atomic mass
|
106.42 g.mol -1
|
|
Electronegativity
according to Pauling
|
2.2
|
|
Density
|
11.9 g.cm-3 at 20°C
|
|
Melting point
|
1560 °C
|
|
Boiling point
|
2927 °C
|
|
Isotopes
|
9
|
|
Vanderwaals
radius
|
0.065 nm (+2)
|
|
Ionic radius
|
0.137 nm
|
|
Electronic
shell
|
[ Kr ] 4d10 5s0
|
|
Energy
of first ionisation
|
703 kJ.mol -1
|
|
Energy of second ionisation |
1870 kJ.mol -1 |
|
Energy of third ionisation |
3177 kJ.mol -1 |
|
Standard potential
|
+ 0.85 V (Pd2+/ Pd )
|
Palladium
Palladium, together with rhodium, ruthenium,
osmium, iridium, and platinum form a group of elements referred to as the
platinum group metals (PGM).
Palladium is a lustrous silver-white metal. It has a face-centered cubic
crystalline structure, at ordinary temperatures it is strongly resistant to corrosion in air and
to the action of acids. It is attacked by hot
acids, and it dissolves in aqua regia. It forms many compounds and
several complex salts. Palladium has a great ability to absorb hydrogen
(up to 900 times its own volume).
Applications
Because of its corrosion resistance, a major use of palladium is in
alloys used in low voltage electrical contacts. When it is finely
divided, palladium forms a good catalyst and is used to speed up
hydrogenation and dehydrogenation reactions.
Palladium is used extensively in jewelry-making in certain alloys
called “white gold.” It may be alloyed with platinum or substituted for
it. It is used in watch bearings, springs, and balance wheels and also
for mirrors in scientific instruments.
In 1990, most catalytic converters relied on platinum to reduce
emissions from car exhausts but, while this metal is still important,
palladium is now the main ingredient because this is even more efficient
at removing unburnt and partially burnt hydrcarbons from the fuel.
Palladium is nowadays more and more used in electrical appliances
such as wide screen televisions, computers and mobile phones, in the
form of tiny multi-layer ceramic capacitors, of which more than 400
billion are made each year.
For use in dentistry it is alloyed with silver, gold, and copper.
Palladium salts are used in electroplating.
Palladium in the environment
Specimen of uncombined palladium are found in Brazil, and there are
some minerals rich in palladium, but most of it is extracted as a
by-product form nickel refining.
Palladium is found as the free
metal associated with platinum and other platinum group metals in
Australia, Brazil, Russia, Ethiopia, and North and South America, as
well as with nickel and copper deposits (from which it is recovered
commercially) in Canada and South Africa.
Back to
the periodic table of elements